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Photochemical & Photobiological Sciences

A society-owned journal publishing high quality research on all aspects of photochemistry and photobiology.



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Contents list for Photochemical & Photobiological Sciences, issue 12, 2008

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Front cover
Photochem. Photobiol. Sci., 2008, 7, 1429
DOI: 10.1039/B820268K

front cover image for Photochemical & Photobiological Sciences, Issue 12, 2008

Contents and Chemical Biology
Photochem. Photobiol. Sci., 2008, 7, 1431
DOI: 10.1039/B820270M

Editorial

Turro the researcher, mentor and teacher
V. Ramamurthy,  Photochem. Photobiol. Sci., 2008, 7, 1441
DOI: 10.1039/b819338j

graphical abstract image (ID: b819338j)

Welcome to the themed issue in honour of Professor N. J. Turro.

Forum

Pitfalls and limitations in the practical use of Förster's theory of resonance energy transfer
Silvia E. Braslavsky, Eduard Fron, Hernán B. Rodríguez, Enrique San Román, Gregory D. Scholes, Gerd Schweitzer, Bernard Valeur and Jakob Wirz,  Photochem. Photobiol. Sci., 2008, 7, 1444
DOI: 10.1039/b810620g

graphical abstract image (ID: b810620g)

Disparate presentations in the literature of the basic equations of Förster's theory of resonance energy transfer are clarified and the limitations of these equations are discussed.

Papers

New insights in the photochromic spiro-dihydroindolizine/betaine-system
Tej B. Shrestha, Junia Melin, Yao Liu, Olga Dolgounitcheva, Viatcheslav G. Zakrzewski, Megh Raj Pokhrel, Eliso Gogritchiani, Joseph Vincent Ortiz, Claudia Turró and Stefan H. Bossmann,  Photochem. Photobiol. Sci., 2008, 7, 1449
DOI: 10.1039/b814151g

graphical abstract image (ID: b814151g)

1,5-Electrocyclic spiro-dihydroindolizine/betaine transition.

Photocyclizable resorcin[4]arene dimers
Christian Schäfer, Frank Strübe, Sebastian Bringmann and Jochen Mattay,  Photochem. Photobiol. Sci., 2008, 7, 1457
DOI: 10.1039/b807700b

graphical abstract image (ID: b807700b)

The synthesis and photochemistry of two resorcin[4]arene dimers 1 and 2 is reported.

Photostability of pentacene and 6,13-disubstituted pentacene derivatives: a theoretical and experimental mechanistic study
Brian H. Northrop, K. N. Houk and Ashok Maliakal,  Photochem. Photobiol. Sci., 2008, 7, 1463
DOI: 10.1039/b813752h

graphical abstract image (ID: b813752h)

Substitution of pentacene with a variety of 6,13 alkynyl groups imparts significant increase in photostability due to decrease in LUMO orbital energy.

Gold nanoparticle photosensitized radical photopolymerization
Kelechi C. Anyaogu, Xichen Cai and Douglas C. Neckers,  Photochem. Photobiol. Sci., 2008, 7, 1469
DOI: 10.1039/b812328d

graphical abstract image (ID: b812328d)

We report the photopolymerization of an acrylic monomer using thiol-stabilized gold nanoparticles and [4-[(octyloxy)phenyl] phenyl] iodonium hexafluoroantimonate as photoinitiator and coinitiator, respectively

Photodimerization and complexation dynamics of coumarins in the presence of cucurbit[8]urils
Nilotpal Barooah, Barry C. Pemberton, Alexander C. Johnson and J. Sivaguru,  Photochem. Photobiol. Sci., 2008, 7, 1473
DOI: 10.1039/b814230k

graphical abstract image (ID: b814230k)

The photodimerization of coumarin within CB[8] is a dynamic process that depends on the nature of the coumarin derivatives.

Dissolution and mineralization of ion exchange resins: differentiation between heterogeneous and homogeneous (photo-)Fenton processes
Monika Zahorodna, Esther Oliveros, Michael Wörner, Romuald Bogoczek and André M. Braun,  Photochem. Photobiol. Sci., 2008, 7, 1480
DOI: 10.1039/b813866b

graphical abstract image (ID: b813866b)

Oxidative degradation of the IER-beads, leading to their apparent dissolution, was initiated by the Fenton reaction of the Fe(II) ions complexed by the sulfonate groups of the IER, whereas mineralization of the organic matter was mainly taking place in the aqueous bulk phase.

Supramolecular complexation and photochirogenesis with inherently chiral molecular clip: enantiodifferentiating photoisomerization of (Z,Z)-1,3-cyclooctadiene and polar photoaddition to 1,1-diphenylpropene
Gaku Fukuhara, Frank-Gerrit Klärner, Tadashi Mori, Takehiko Wada and Yoshihisa Inoue,  Photochem. Photobiol. Sci., 2008, 7, 1493
DOI: 10.1039/b812186a

graphical abstract image (ID: b812186a)

Chiral molecular clip with naphthalene chromophores sensitizes the ZE photoisomerization but does not mediate the polar photoaddition.

Photoinduced charge separation in pyrenedicarboxamide-linked DNA hairpins
Pierre Daublain, Karsten Siegmund, Mahesh Hariharan, Josh Vura-Weis, Michael R. Wasielewski, Frederick D. Lewis, Vladimir Shafirovich, Qiang Wang, Milen Raytchev and Torsten Fiebig,  Photochem. Photobiol. Sci., 2008, 7, 1501
DOI: 10.1039/b813995d

graphical abstract image (ID: b813995d)

Irradiation of pyrenedicarboxamide-linked hairpins results in the efficient formation of long-lived charge-separated states.

Photophysical study of bay substituted perylenediimides
Eduard Fron, Gerd Schweitzer, Peter Osswald, Frank Würthner, Philippe Marsal, David Beljonne, Klaus Müllen, Frans C. De Schryver and Mark Van der Auweraer,  Photochem. Photobiol. Sci., 2008, 7, 1509
DOI: 10.1039/b813737d

graphical abstract image (ID: b813737d)

Femtosecond transient absorption and single photon timing experiments reveal conformational dynamics and charge transfer in a series of perylenediimide systems bearing different types of bay substituents.

Towards building artificial light harvesting complexes: enhanced singlet–singlet energy transfer between donor and acceptor pairs bound to albumins
Challa V. Kumar, Michael R. Duff and Jr.,  Photochem. Photobiol. Sci., 2008, 7, 1522
DOI: 10.1039/b811091c

graphical abstract image (ID: b811091c)

Self-assembly of donor and acceptor chromophores in a protein host facilitated efficient donor to acceptor singlet–singlet energy transfer even at micromolar concentrations of the acceptor.

Inorganic photochemical protein scissors: photocleavage of lysozyme by Co(III) complexes
Thota Jyotsna, Kalpanie Bandara and Challa V. Kumar,  Photochem. Photobiol. Sci., 2008, 7, 1531
DOI: 10.1039/b810422k

graphical abstract image (ID: b810422k)

Photo-induced protein cleavage by several Co(III) complexes.

Kinetics of geminate recombination of organic free radicals in viscous solvents
Igor Khudyakov, Peter Levin and Vladimir Kuzmin,  Photochem. Photobiol. Sci., 2008, 7, 1540
DOI: 10.1039/b810884f

graphical abstract image (ID: b810884f)

Geminate recombination of organic multiatomic free radicals in glycerol proceeds longer than the theoretically expected duration of the process based on the assumption that the mutual diffusion coefficient D12 = D1 + D2.

Direct and water-mediated excited state intramolecular proton transfer (ESIPT) from phenol OH to carbon atoms of extended ortho-substituted biaryl systems
Manoj Kumar Nayak and Peter Wan,  Photochem. Photobiol. Sci., 2008, 7, 1544
DOI: 10.1039/b810111f

graphical abstract image (ID: b810111f)

The formal ESIPT from phenol OH to carbon atoms of ortho-substituted benzene rings as studied by deuterium exchange indicates that transfer to the system is due to a direct process that results in protonation at proximal positions and a water-mediated process that results in protonation at distal positions.

Consequences of controlling free space within a reaction cavity with a remote alkyl group: photochemistry of para-alkyl dibenzyl ketones within an organic capsule in water
Arun Kumar Sundaresan and V. Ramamurthy,  Photochem. Photobiol. Sci., 2008, 7, 1555
DOI: 10.1039/b814001d

graphical abstract image (ID: b814001d)

Photoreactions within a confined space are subject to the availability of free space for the reacting guest molecule.

Biocidal performance of acrylated glyphosate in a model photopolymerizable coating formulation
Victoria Piunova, Daniel Berger, Douglas C. Neckers, George S. Bullerjahn, R. Michael McKay and Andrei V. Fedorov,  Photochem. Photobiol. Sci., 2008, 7, 1565
DOI: 10.1039/b809659g

graphical abstract image (ID: b809659g)

Acrylated glyphosate was photopolymerized as a part of polyolacrylate formulation with the resulting photopolymer retaining herbicidal activity similar to that of the monomer.

Synthesis and photo-conversion of androsta- and pregna-5,7-dienes to vitamin D3-like derivatives
Michal A. Zmijewski, Wei Li, Jordan K. Zjawiony, Trevor W. Sweatman, Jianjun Chen, Duane D. Miller and Andrzej T. Slominski,  Photochem. Photobiol. Sci., 2008, 7, 1570
DOI: 10.1039/b809005j

graphical abstract image (ID: b809005j)

We describe dynamic UVB induced conversion of androsta- and pregna-5,7-dienes into vitamin D-like compounds.

A yellow chlorophyll catabolite is a pigment of the fall colours
Simone Moser, Markus Ulrich, Thomas Müller and Bernhard Kräutler,  Photochem. Photobiol. Sci., 2008, 7, 1577
DOI: 10.1039/b813558d

graphical abstract image (ID: b813558d)

Senescent leaves of a deciduous tree were found to contain a yellow tetrapyrrole, giving first evidence for an active contribution of chlorophyll catabolites to the fall colours.

Back matter
Photochem. Photobiol. Sci., 2008, 7, 1582
DOI: 10.1039/B820271K

Back cover
Photochem. Photobiol. Sci., 2008, 7, 1583
DOI: 10.1039/B820272A