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Dalton Transactions

The leading European journal for inorganic and organometallic chemistry



Dalton Perspectives


Dalton Perspectives are invited personal accounts or critical analyses of activities in specialist areas and are intended to be high profile articles of interest to a broad spectrum of research workers.



Transition metal catalysed reactions of alcohols using borrowing hydrogen methodology
Tracy D. Nixon, Michael K. Whittlesey and Jonathan M. J. Williams, Dalton Trans., 2009
DOI: 10.1039/b813383b


Bioinorganic chemistry of copper and zinc ions coordinated to amyloid- peptide
Peter Faller and Christelle Hureau, Dalton Trans., 2009
DOI: 10.1039/b813398k


myo-Inositol oxygenase: a radical new pathway for O2 and C–H activation at a nonheme diiron cluster
J. Martin Bollinger Jr. , Yinghui Diao, Megan L. Matthews, Gang Xing and Carsten Krebs, Dalton Trans., 2009
DOI: 10.1039/b811885j


Recent developments in the coordination chemistry of bis(imino)acenaphthene (BIAN) ligands with s- and p-block elements
Nicholas J. Hill, Ignacio Vargas-Baca and Alan H. Cowley, Dalton Trans., 2009
DOI: 10.1039/b815079f


Stereochemistry of free boranes and heteroboranes from electron scattering and model chemistries
Drahomír Hnyk and David W. H. Rankin, Dalton Trans., 2009
DOI: 10.1039/b806774k


DNA-binding drugs caught in action: the latest 3D pictures of drug-DNA complexes
D. Roeland Boer, Albert Canals and Miquel Coll, Dalton Trans., 2009
DOI: 10.1039/b809873p


Metal-phosphido and -phosphinidene complexes in P–E bond-forming reactions
Rory Waterman, Dalton Trans., 2009
DOI: 10.1039/b813332h


DNA hydrolytic cleavage catalyzed by synthetic multinuclear metallonucleases
Changlin Liu and Li Wang, Dalton Trans., 2009
DOI: 10.1039/b811616d


-Conjugated phosphole derivatives: synthesis, optoelectronic functions and coordination chemistry
Jeanne Crassous and Régis Réau, Dalton Trans., 2008, 6865
DOI: 10.1039/b810976a


Plant MTs—long neglected members of the metallothionein superfamily
Eva Freisinger, Dalton Trans., 2008, 6663
DOI: 10.1039/b809789e


Bifunctional catalysts and related complexes: structures and properties
Douglas B. Grotjahn, Dalton Trans., 2008, 6497
DOI: 10.1039/b809274e


Multidentate ligand systems featuring dual functionality
Istemi Kuzu, Ivo Krummenacher, Jens Meyer, Felix Armbruster and Frank Breher, Dalton Trans., 2008, 5836
DOI: 10.1039/b808347a


N-Heterocyclic carbenes/imidazolium salts as substrates in catalysis: the catalytic 2-substitution and annulation of heterocyclic compounds
Kingsley Cavell, Dalton Trans., 2008, 6676
DOI: 10.1039/b811449h


Supramolecular approach for solid state Brownian rotators
Tomoyuki Akutagawa and Takayoshi Nakamura, Dalton Trans., 2008, 6335
DOI: 10.1039/b808748b


Unconventional metal organic frameworks: porous cross-linked phosphonates
Abraham Clearfield, Dalton Trans., 2008, 6089
DOI: 10.1039/b807676f


Ring expansions and contractions of metalloporphyrins
Henry J. Callot, Dalton Trans., 2008, 6346
DOI: 10.1039/b807066k


Well-defined polynuclear heterobimetallic complexes as precursors for ceramic and magnetic materials
Sawomir Szafert, ukasz John and Piotr Sobota, Dalton Trans., 2008, 6509
DOI: 10.1039/b806167j


Luminescent rare earth nanomaterials for bioprobe applications
Jie Shen, Ling-Dong Sun and Chun-Hua Yan, Dalton Trans., 2008, 5687
DOI: 10.1039/b805306e


Metal and mixed-metal coordination polymers synthesized with pyrazine-2-carboxylate
Joseph M. Ellsworth and Hans-Conrad zur Loye, Dalton Trans., 2008, 5823
DOI: 10.1039/b807227b


Bonding properties and bond activation of ylides: recent findings and outlook
Esteban P. Urriolabeitia, Dalton Trans., 2008, 5673
DOI: 10.1039/b806787b


Diol-type ligands as central players in the chemistry of high-spin molecules and single-molecule magnets
Anastasios J. Tasiopoulos and Spyros P. Perlepes, Dalton Trans., 2008, 5537
DOI: 10.1039/b805014g


Recent developments in the chemistry of low valent Group 14 hydrides
Eric Rivard and Philip P. Power, Dalton Trans., 2008, 4336
DOI: 10.1039/b801400k


Hydrogen-rich boron-containing materials for hydrogen storage
Ping Wang and Xiang-dong Kang, Dalton Trans., 2008, 5400
DOI: 10.1039/b807162d


Metal-catalyzed nucleophilic carbon–heteroatom (C–X) bond formation: the role of M–X intermediates
David S. Glueck, Dalton Trans., 2008, 5276
DOI: 10.1039/b806138f


Inorganic nanomaterials for batteries
M. Stanley Whittingham, Dalton Trans., 2008, 5424
DOI: 10.1039/b806372a


Nanocrystalline gold and gold–palladium alloy oxidation catalysts: a personal reflection on the nature of the active sites
Graham J. Hutchings, Dalton Trans., 2008, 5523
DOI: 10.1039/b804604m


The role of external lone pairs in the chemical bonding of bare post-transition element clusters: the Wade–Mingos rules versus the jellium model
R. B. King and I. Silaghi-Dumitrescu, Dalton Trans., 2008, 6083
DOI: 10.1039/b803958e


Polymeric materials based on main group elements: the recent development of ambient temperature and controlled routes to polyphosphazenes
Vivienne Blackstone, Alejandro Presa Soto and Ian Manners, Dalton Trans., 2008, 4363
DOI: 10.1039/b719361k


Formation, structure and bonding of metalloid Al and Ga clusters. A challenge for chemical efforts in nanosciences
Hansgeorg Schnöckel, Dalton Trans., 2008, 4344
DOI: 10.1039/b718784j


The coordination chemistry of group 15 element ligand complexes—a developing area
Manfred Scheer, Dalton Trans., 2008, 4372
DOI: 10.1039/b718179p


Functional carbonaceous materials from hydrothermal carbonization of biomass: an effective chemical process
Bo Hu, Shu-Hong Yu, Kan Wang, Lei Liu and Xue-Wei Xu, Dalton Trans., 2008, 5414
DOI: 10.1039/b804644c


Design and its limitations in the construction of bi- and poly-nuclear coordination complexes and coordination polymers (aka MOFs): a personal view
R. Robson, Dalton Trans., 2008, 5113
DOI: 10.1039/b805617j


Rotaxanes and pseudorotaxanes with Fe-, Pd- and Pt-containing axles. Molecular motion in the solid state and aggregation in solution
Yuji Suzaki, Toshiaki Taira, Kohtaro Osakada and Masaki Horie, Dalton Trans., 2008, 4823
DOI: 10.1039/b804125c


Metal complex-assisted activation of small molecules. From NO to superoxide and peroxides
Ivana Ivanovi-Burmazovi and Rudi van Eldik, Dalton Trans., 2008, 5259
DOI: 10.1039/b805450a


Nitrogen-15 NMR spectroscopy of N-metallated nucleic acids: insights into 15N NMR parameters and N–metal bonds
Yoshiyuki Tanaka and Akira Ono, Dalton Trans., 2008, 4965
DOI: 10.1039/b803510p


FeII/-ketoglutarate hydroxylases involved in nucleobase, nucleoside, nucleotide, and chromatin metabolism
Jana M. Simmons, Tina A. Müller and Robert P. Hausinger, Dalton Trans., 2008, 5132
DOI: 10.1039/b803512a


Hydrogenated tetraazaporphyrins—old but new core-modified phthalocyanine analogues
Takamitsu Fukuda and Nagao Kobayashi, Dalton Trans., 2008, 4685
DOI: 10.1039/b804181d


N-Heterocyclic carbene complexes of rhodium: structure, stability and reactivity
Jeremy M. Praetorius and Cathleen M. Crudden, Dalton Trans., 2008, 4079
DOI: 10.1039/b802114g


Unconventional electronic and magnetic functions of nanographene-based host–guest systems
Toshiaki Enoki and Kazuyuki Takai, Dalton Trans., 2008, 3773
DOI: 10.1039/b800138n


Activation of late transition metal catalysts for olefin polymerizations and olefin/CO copolymerizations
Timo M. J. Anselment, Sergej I. Vagin and Bernhard Rieger, Dalton Trans., 2008, 4537
DOI: 10.1039/b802913j


Dechlorination of chloroethylenes by cob(I)alamin and cobalamin model complexes
Sarah Kliegman and Kristopher McNeill, Dalton Trans., 2008, 4191
DOI: 10.1039/b801679h


Nucleobase-containing transition metal complexes as building blocks for biological markers and supramolecular structures
Jason M. Lynam, Dalton Trans., 2008, 4067
DOI: 10.1039/b802347f


O2 Reduction to H2O by the multicopper oxidases
Edward I. Solomon, Anthony J. Augustine and Jungjoo Yoon, Dalton Trans., 2008, 3921
DOI: 10.1039/b800799c


Charged ligands for catalyst immobilisation and analysis
Danielle M. Chisholm and J. Scott McIndoe, Dalton Trans., 2008, 3933
DOI: 10.1039/b800371h


The coordination chemistry of nitrosyl in cyanoferrates. An exhibit of bioinorganic relevant reactions
José A. Olabe, Dalton Trans., 2008, 3633
DOI: 10.1039/b803153c


Ligand design for multidimensional magnetic materials: a metallosupramolecular perspective
Emilio Pardo, Rafael Ruiz-García, Joan Cano, Xavier Ottenwaelder, Rodrigue Lescouëzec, Yves Journaux, Francesc Lloret and Miguel Julve, Dalton Trans., 2008, 2780
DOI: 10.1039/b801222a


Chemistry of polycarbon species: from clusters to molecular devices
Munetaka Akita and Takashi Koike, Dalton Trans., 2008, 3523
DOI: 10.1039/b802069h


Photochrome-coupled metal complexes: molecular processing of photon stimuli
Shoko Kume and Hiroshi Nishihara, Dalton Trans., 2008, 3260
DOI: 10.1039/b716947g


Perspectives in paramagnetic NMR of metalloproteins
Ivano Bertini, Claudio Luchinat, Giacomo Parigi and Roberta Pierattelli, Dalton Trans., 2008, 3782
DOI: 10.1039/b719526e


Gadolinium(III) complexes as MRI contrast agents: ligand design and properties of the complexes
Petr Hermann, Jan Kotek, Vojtch Kubíek and Ivan LukeDalton Trans., 2008, 3027
DOI: 10.1039/b719704g


QM/MM methods in inorganic chemistry
Carles Bo and Feliu Maseras, Dalton Trans., 2008, 2911
DOI: 10.1039/b718076d


Metal-containing sensor proteins sensing diatomic gas molecules
Shigetoshi Aono, Dalton Trans., 2008, 3137
DOI: 10.1039/b802070c


Cobalt–rhodium heterobimetallic nanoparticle-catalyzed reactions
Ji Hoon Park and Young Keun Chung, Dalton Trans., 2008, 2369
DOI: 10.1039/b718609f


Ionic liquid electrolytes for dye-sensitized solar cells
Mikhail Gorlov and Lars Kloo, Dalton Trans., 2008, 2655
DOI: 10.1039/b716419j


Subporphyrins: emerging contracted porphyrins with aromatic 14-electronic systems and bowl-shaped structures: rational and unexpected synthetic routes
Yasuhide Inokuma and Atsuhiro Osuka, Dalton Trans., 2008, 2517
DOI: 10.1039/b719808f


Light-emitting iridium complexes with tridentate ligands
J. A. Gareth Williams, Andrew J. Wilkinson and Victoria L. Whittle, Dalton Trans., 2008, 2081
DOI: 10.1039/b716743a


Hydride encapsulation by molecular alkali-metal clusters
Joanna Haywood and Andrew E. H. Wheatley, Dalton Trans., 2008, 3378
DOI: 10.1039/b717563a


Bis-phosphorus stabilised carbene complexes
Thibault Cantat, Nicolas Mézailles, Audrey Auffrant and Pascal Le Floch, Dalton Trans., 2008, 1957
DOI: 10.1039/b717600g


Cyclic oxonium derivatives of polyhedral boron hydrides and their synthetic applications
Andrey A. Semioshkin, Igor B. Sivaev and Vladimir I. Bregadze, Dalton Trans., 2008, 977
DOI: 10.1039/b715363e


The fluorolytic sol–gel route to metal fluorides—a versatile process opening a variety of application fields
Stephan Rüdiger and Erhard Kemnitz, Dalton Trans., 2008, 1117
DOI: 10.1039/b716483a


Ligand directed self-assembly of polymetallic [n × n] grids: rational routes to large functional molecular subunits?
Louise N. Dawe, Tareque S. M. Abedin and Laurence K. Thompson, Dalton Trans., 2008, 1661
DOI: 10.1039/b716114j


Ground state spin-switching via targeted structural distortion: twisted single-molecule magnets from derivatised salicylaldoximes
Constantinos J. Milios, Stergios Piligkos and Euan K. Brechin, Dalton Trans., 2008, 1809
DOI: 10.1039/b716355j


Pd-catalysed asymmetric mono- and bis-alkoxycarbonylation of vinylarenes
Cyril Godard, Bianca K. Muñoz, Aurora Ruiz and Carmen Claver, Dalton Trans., 2008, 853
DOI: 10.1039/b714809g


Towards the rational design of platinum(II) and gold(III) complexes as antitumour agents
Xiaoyong Wang and Zijian Guo, Dalton Trans., 2008, 1521
DOI: 10.1039/b715903j


Multinuclear self-assembly via half-sandwich complexes Cp*M[S2C2(B10H10)] and pyridine-based ligands
Shuang Liu, Guo-Liang Wang and Guo-Xin Jin, Dalton Trans., 2008, 425
DOI: 10.1039/b712590a


Luminescent heteropolynuclear or multicomponent complexes with polypyridyl-functionalized alkynyl ligands
Zhong-Ning Chen, Yang Fan and Jun Ni, Dalton Trans., 2008, 573
DOI: 10.1039/b713582c


Digital microfluidics and delivery of molecular payloads with magnetic porous silicon chaperones
Jason R. Dorvee, Michael J. Sailor and Gordon M. Miskelly, Dalton Trans., 2008, 721
DOI: 10.1039/b714594b


One-N, six-membered heterocyclic carbene complexes and the remote heteroatom concept
Helgard G. Raubenheimer and Stephanie Cronje, Dalton Trans., 2008, 1265
DOI: 10.1039/b715592a


Doubly bonded systems between heavier Group 15 elements
Takahiro Sasamori and Norihiro Tokitoh, Dalton Trans., 2008, 1395
DOI: 10.1039/b715033d


Modelling NiFe hydrogenases: nickel-based electrocatalysts for hydrogen production
Sigolène Canaguier, Vincent Artero and Marc Fontecave, Dalton Trans., 2008, 315
DOI: 10.1039/b713567j


Antitumour metal compounds: more than theme and variations
Michael A. Jakupec, Markus Galanski, Vladimir B. Arion, Christian G. Hartinger and Bernhard K. Keppler, Dalton Trans., 2008, 183
DOI: 10.1039/b712656p


Self-assembly in inorganic and hybrid systems: beyond the molecular scale
Markus Antonietti, Markus Niederberger and Bernd Smarsly, Dalton Trans., 2008, 18
DOI: 10.1039/b711529f


Dalton Perspectives 2007

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Dalton Perspectives 2006

Browse Dalton Perspectives from 2006 here