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Chemical Communications

Urgent high quality communications from across the chemical sciences.



Hot Articles



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Hot article: Organofluorine functional molecules

02 December 2008

Japanese scientists synthesise difluoroketone derivatives; potential HIV inhibitors.



Raney nickel catalyses the monalkylation of primary amines and N-sulfinylamides in alcohol

Hot article: Chemistry for a Raney day

28 November 2008

Scientists have stumbled across a new way to monoalkylate amines that they claim is more environmentally friendly than alternative routes



Model with synthetic Naq shown as an amino acid in an alpha-helix (poly-leucine)

Hot article: How do you convert energy?

27 November 2008

US scientists have created an artificial amino acid to help investigate the way proteins capture energy.



cis-(1R,2S)-1,2-dihydro-1,2-naphthalenediol

Iron complex mimics soil bacteria

26 November 2008

Scientists in the US report the first synthetic compound to catalyse a key step in the degradation of double bonds in aromatic rings



Fullerene blended with polymer

Hot article: Getting to grips with solar cells

17 November 2008

UK scientists provide a new insight into the parameters that determine the efficiency of organic solar cells.



TATP structure

Glowing report for explosive detection

14 November 2008

Israeli scientists have developed a sensitive method for detecting an explosive used by terrorists.



N-substituted pyrazole dialdehydes are shown to react with a tripyrrane under 3 + 1 conditions to give aza-analogues of the N-confused porphyrins. These novel porphyrinoids show borderline aromatic properties and readily afford organometallic derivatives (M = Ni or Pd).

Hot article: Adding to the confusion

13 November 2008

US scientists show that N-substituted pyrazole dialdehydes react with tripyrrane to give aza-analogues of N-confused porphyrins.



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Hot article: Finding a catalyst

12 November 2008

US scientists present a general strategy for the fast and efficient screening of catalysts for atom transfer radical polymerisation.



Contact angle on film when irradiated in DMF

Hot article: Brushing up on sensors

11 November 2008

Polymer brushes for reversible, photoswitchable optical sensors that selectively bind metal ions have been developed in the US.



Indium(I) halide complex

Hot article: Soluble indium halide reagents

11 November 2008

A soluble, metastable indium(I) halide complex has been synthesised and characterised by scientists in Australia.



Molecular structure

Hot article: Mechanical calculations for methyl transfer in solution

10 November 2008

UK scientists have studied kinetic isotope effects for reactions in enzymes and in solutions.



Nanoparticle dispersion inside a magnetic field

Magnetic solution for sticky problem

07 November 2008

Belgian scientists have discovered a new method to stop nanoparticles sticking together



anti-beta-hydroxy-alpha-amino ester

Hot article: Transition to sustainable catalysis

07 November 2008

Japanese scientists have discovered a cheap and enantioselective catalyst for asymmetric hydrogenation reactions.



A variety of ary and heteroaryl bromides were cross-coupled with ammonia in good to high yields in the presence of a copper-NHC catalyst.

Hot Article: Cross-coupling with a copper-carbene catalyst

07 November 2008

Canadian scientists have developed a new copper carbene catalyst for synthesising primary aromatic amines in excellent yields.



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Hot article: Thioesters for native chemical ligation

05 November 2008

3-Mercaptopropionic acid-mediated synthesis of peptide and protein thioesters carried out by UK researchers.



Fingerprint

Fingerprints show their dark side

04 November 2008

A new fingerprinting method could help forensic scientists detect prints on almost any surface



Silanethione may exist in space

Silanethiones reach for the stars

04 November 2008

German researchers have identified experimentally H2Si=S, a molecule thought to exist in outer space, for the first time.



structure of the multi-functional organometallic switch

Hot article: Multi-functional organometallic switch

04 November 2008

French chemists have created a multi-functional organometallic switch which can be triggered using either light or electric potential.



PPE-2 in lyotropic liquid crystal matrix

Hot Article: Polymers organised in liquid crystals

04 November 2008

Supramolecular self-assembly of amphiphilic polymers in lyotropic liquid crystal matrix



Catalyst structure

Fluorination gets a good reaction

30 October 2008

European chemists have used fluorinated solvents to improve the yields of olefin metathesis reactions



Thin film

New spin on electronics production

24 October 2008

Chemists have taken a significant step closer to the goal of cheap, flexible and printable organic electronic displays



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Hot article: Cyclic Peptoid Microarrays

21 October 2008

US scientists have developed encoded combinatorial libraries for the construction of cyclic peptoid microarrays.



chiral metal-organic framework synthesised using chemoenzymatic synthesis

Hot articles: From Enzymes to MOFs

14 October 2008

UK scientists have used dioxygenase enzymes to create enantiopure organic molecules, which in turn have been used to create chiral metal-organic frameworks.



Quantum dot

Quantum leap in chemical sensing

08 October 2008

UK scientists have found that quantum dots can improve optical sensors designed for detecting metal ions in water



A molecular model of a diphenyl urea bound to G4 DNA

Quadruplex binding clicks into place

06 October 2008

Ureas that shun the double helix for four-stranded DNA could lead to new anticancer drugs, say UK scientists



A molecular beacon that incorporates components of an artificially expanded genetic information system (AEGIS) in its stem is shown not to be opened by unwanted stem invasion by adventitious standard DNA. This should improve the darkness of the beacon in real-world applications

Hot article: Improved darkness of molecular beacon

02 October 2008

A new tool that reduces the detection of non-targeted DNA has been designed by researchers from the US.